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  HI&I   |   Fluorinated Surfactants - Personal Care  
   
 
Masurf® FS-Fluorosurfactants - Personal care
   
With typical use concentrations of an economical 50-500ppm, Fluorosurfactants provide predictable wetting, leveling and surface tension reduction properties not possible with hydrocarbon, acetylenic or silicone surfactants for use in a wide range of applications including personal care products. Fluorosurfactants can also impart significant oil and sebum resistance to treated substrates.

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Grade
Structure
Description/Attributes
Masurf FS-130A


Related Products: Zonyl* FSP, FSJ, Zonyl 7950
MASURF FS-130A is a 30% active ammonium fluoroaliphatic phosphate ester in an aqueous solution. FS-130A contributes oil, grease and sebum resistance, conditioning, wetting and lubricity. FS-130A is free of alcohols and solvents.
INCI Name: Ammonium-C6-16 Perfluoroalkylethyl Phosphate
Masurf FS-115/FS-130


Related Products: Zonyl* RP, Zonyl 9027, 9361
Fluorad* FC-807
MASURF FS-115 and FS-130 are characterized as 14% and 28% active aqueous fluoroaliphatic phosphate ester fluorosurfactant solutions. MASURF FS-115/FS130 is an FDA approved for Food Contact applications. FS-115/FS-130 is a water dispersible fluoroaliphatic agent that imparts a high degree of oil and grease resistance to a wide range of surfaces and substrates.
INCI Name: DEA-C8-18 Perfluoroalkylethyl Phosphate
Masurf FS-1520

Related Products: Fluorad* FC-100, Zonyl* FSK
MASURF FS-1520 is a 20% active fluoroaliphatic betaine in a propylene glycol/water solution. FS-1520 is a superior surface tension reduction agent for wetting, exhibiting high foam with high electrolyte tolerance.
INCI Name: Polytetrafluoroethylene Acetoxypropyl Betaine
Masurf FS-1620

Related Products: Fluorad* FC-129, FC-135, Zonyl* FSD
MASURF FS-1620 is a 20% active fluoroaliphatic quaternary in an aqueous solution. FS-1620 is a superior surface tension reduction agent for wetting, exhibiting high foam with high electrolyte tolerance.
INCI Name: C4-18 Perfluoroalkylethyl Thiohydroxypropyltrimonium Chloride
*Fluorad and Zonyl are Registered Trademarks of the 3M Company and the E.I. du Pont de Nemours and Company respectively.

 
  Structure/Function relationship of Fluorosurfactants
The structure below illustrates a typical hydrocarbon surfactant, with a hydrophobic/lipophilic tail and a hydrophilic/lipophobic head. Hydrocarbon surfactants tend to orient and concentrate at condensed phase interfaces, i.e. liquid/liquid, liquid/solid. Typical hydrocarbon surfactants cannot function as wetting/leveling agents in organic, high solids, non-aqueous or other oily phase systems, given the nature of their lipophilic tail.

     
  Hydrocarbon Lipophilic/Hydrophobic Tail Hydrophilic Head
  The structure below illustrates a typical fluorocarbon surfactant, with the carbon fluorine attachment (CF2). In contrast to the hydrocarbon surfactant structure above, fluorocarbon surfactants differ discretely but significantly. Instead of a hydrophobic/lipophilic tail and a hydrophilic/lipophobic head, fluorocarbon surfactants posses a fluoroalkyl hydrophobic/lipophobic tail and what should be characterized as a solubilizing head. Where hydrocarbon surfactants tend to orient and concentrate at condensed phase interfaces, fluorocarbon surfactants concentrate at the liquid air interface.

   
  Fluorocarbon Lipophobic/Hydrophobic Tail Solubilizing Head
  The strong electronegativity of the fluoroalkyl chain drives fluorosurfactants to the liquid air interface, resulting in dramatic reductions in surface tension compared with hydrocarbon surfactants that concentrate at condensed phases. Given the nature of the fluoroalkyl tail, fluorosurfactants function well as wetting/leveling agents in organic, high solids, non-aqueous or other oily phase systems, as well as in aqueous systems, and can impart oil and grease resistance to treated substrates.

Masurf FS-Fluorosurfactants and Masurf FP-Fluoropolymers do not contain PFOS/PFOA. Masurf FS and FP products are manufactured with telomerization process fluoroaliphatic intermediates that do not contain, release or have been shown to degrade to perfluorooctane sulfonate (PFOS) or perfluorooctanoic acid (PFOA).
   
  MAC V.010504
 
 
 
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