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Masurf® FS-425
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Fluoroaliphatic Polyoxyethylene Fluorosurfactant
 
 

MASURF FS-425 is characterized as a 25% active fluoroaliphatic polyoxyethylene fluorosurfactant in a water/glycol ether solution. FS-425 is a nonionic fluorosurfactant with the ability to contribute exceptional wetting, spreading and leveling properties to a wide range of systems. With typical use levels of 50-500ppm, MASURF FS-425 is effective at very low concentrations, and together with traditional hydrocarbon surfactants, can contribute properties not possible with either material alone.

MASURF FS-425 is stable in anionic and cationic systems, effective in high or low pH, and recommended in a wide range of applications. With unique surface diffusion properties, FS-425 imparts anti-soiling and improved weatherability when formulated into Coatings and Sealers. In Performance Polymer Systems, FS-425 acts as a coupling agent for fillers, and imparts anti-soiling performance. In Plating Applications, FS-425 improves stability of bath and contributes to brightness and adhesion. In Ink (flexographic or gravure) applications, overall performance can be improved by using a blend of Masurf FS-425 with acetylenic surfactants, and is useful in avoiding “solvent shock” in ink/solvent letdowns.
MASURF FS-4100 available as 100% active material.

Physical form Light yellow liquid, with mild alcohol odor
Actives content % 24 wt% minimum
Aqueous surface tension @25°C dynes/cm 25@0.001%, 17@0.01%, 17 lowest
Interfacial tension (0.1%aq./cyclohexane) 10 dynes/cm
Specific gravity @25°C 1.10±0.04
pH 6.0±1.5
Viscosity @25°C <100 cps
Flash point (TCC) >200°F / 93°C
VOC content (volatile-water) 25% (2-Butoxyethanol)
Storage Store above 32°F and below 100°F

Handling Information

Refer to the Material Safety Data Sheet (MSDS) available from Mason Chemical Company for information on the safe use, handling and disposal of this product.

MASURF FS-425 is characterized as a 25% active fluoroaliphatic polyoxyethylene fluorosurfactant in a water/2-butoxyethanol solution. FS-425 is an effective wetting and interfacial tension reducing agent with very good alkaline stability. The formulation below illustrates this effect.

Scrubless Floor Stripper
Ingredients: Wt.%
Water 64.9
Sodium Hydroxide, 50% (1) 3.0
Potassium Hydroxide, 45% (1) 2.5
Sodium Silicate, "N" Clear (1) 7.5
Na4EDTA, 38% 2.0
Nonylphenol 9.5ETO 1.0
Sodium Xylene Sulfonate, 40% 4.0
Monoethanolamine (2) 5.0
Ethyleneglycol monobutylether (3) 2.0
Diethyleneglycol monobutylether (3) 8.0
Masurf FS-425 0.1
Notes:
Mix in order listed.
Mixtures of Sodium and Potassium contribute to improved stability of highly alkaline, built formulations.
Monoethanolamine breaks the "zinc interlock" in high durability floor finishes
Mixtures of solvents for softening of "burnished" floor finishes

When formulating Hard Surface cleaners, the acronym "TACT" should be kept in mind: T (Time), A (Agitation), C (Concentration) and T (Temperature). Leverage any component of TACT for improved cleaning performance and efficiency. MASURF FS-425 is effective at reducing the required contact time (T) by increasing wetting performance and penetration, and increasing the effective concentration (C) by lowering the interfacial tension between the detergent surfactants, monoethanolamine, solvents and the polymer floor finish.

Ink (flexographic or gravure) applications
Unlike many fluorosurfactants, Masurf FS-425 is a low foamer and performs in inks to deliver improvements in flow, wetting, leveling, gloss, and reduction of surface imperfections.

Acetylenic alcohol based surfactants provide exceptional dynamic surface tension reduction, getting to their minimum surface tension faster than most fluorosurfactants. However, the acetylenic alcohol based materials can only reduce the surface tension to a level like most hydrocarbon surfactants. In ink applications (whether flexographic or gravure), performance improvements can be made by using a blend of fluorosurfactants with the acetylenic alcohol based surfactants to get the instant reduction, followed in the next instant by the fluorosurfactant surface reduction to the lowest possible surface tension possible. Dynamic surface tension reduction data consistently show that the way to get the fastest reduction AND the greatest magnitude of reduction (which ultimately is what improves leveling and decreases ink wicking the most) is to use a 1:1 mixture of a nonionic fluorosurfactant like Masurf FS-425 in combination with an acetylenic alcohol based surfactant.

Additionally, nonionic fluorosurfactants such as Masurf FS-425 are often are helpful in avoiding “solvent shock,” when ink concentrates are “letdown” to final concentrations. Mixing in a small amount of FS-425 to the concentrate immediately prior to letting it down can avoid solids coming out of solution.

Masurf FS-Fluorosurfactant evaluation guidelines
Masurf FS-Fluorosurfactants are effective at very low concentrations, typically 50-500 ppm, and can act synergistically with hydrocarbon and/or silicone surfactants. Evaluate in aqueous formulations at 0.1% active Masurf FS-Fluorosurfactant initially, then optimize by successively reducing the FS concentration by ½.

Masurf FS-Fluorosurfactants and Masurf FP-Fluoropolymers do not contain PFOS/PFOA. Masurf FS and FP products are manufactured with telomerization process fluoroaliphatic intermediates that do not contain, release or have been shown to degrade to perfluorooctane sulfonate (PFOS) or perfluorooctanoic acid (PFOA).
 
       
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